Crystal structure of the η4-ketimine titanium complex (diphenylamido-κN){3-methyl-6-[(4-methylphenyl)(phenylazanidyl)methylidene]cyclohexa-2,4-dien-1-yl-κ2 N,C1}(η5-pentamethylcyclopentadienyl)titanium(IV)
Fischer M., Schmidtmann M., Beckhaus R.
The molecular structure of the title titanium(IV) half-sandwich complex, [Ti(η5-C10H15)(η4-C21H19N)(C12H10N)], shows a three-legged piano-stool geometry at the central TiIV atom, comprising of one pentamethylcyclopentadienyl ligand, one bidentate ketimine ligand in an η4-coordination mode and one monodentate diphenylamide ligand. Except for van der Waals forces, there are no significant intermolecular interactions in the crystal.