Teaching: C -phosphanylimines the titanaaziridine coordination mode
Fischer M., Steinert H., Schmidtmann M., Beckhaus R.
The c-phosphanylimine L1 was employed for the synthesis of the novel titanaaziridine 1 with an intramolecular phosphine donor side following a reductive complexation route. This coordination mode is new for c-phosphanylimines and compound 1 is the first group 4 complex featuring a c-phosphanylimine ligand.