Intermolecular Hydroaminoalkylation of Propadiene
Kaper T., Fischer M., Warsitz M., Zimmering R., Beckhaus R., Doye S.
Intermolecular hydroaminoalkylation reactions of propadiene with selected secondary amines take place in the presence of a 2,6-bis(phenylamino)pyridinato titanium catalyst. The corresponding products, synthetically useful allylamines, are formed in convincing yields and with high selectivities. In addition, propadiene easily inserts into the titanium-carbon bond of a titanaaziridine.