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The molecular structure of the title titanium(IV) half-sandwich complex, [Ti(η5-C10H15)(η4-C21H19N)(C12H10N)], shows a three-legged piano-stool geometry at the central TiIV atom, comprising of one pentamethylcyclopentadienyl ligand, one bidentate ketimine ligand in an η4-coordination mode and one monodentate diphenylamide ligand. Except for van der Waals forces, there are no significant intermolecular interactions in the crystal.

Original publication

DOI

10.1107/S2056989017017455

Type

Journal article

Journal

Acta Crystallographica Section E: Crystallographic Communications

Publication Date

01/01/2018

Volume

74

Pages

34 - 37