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Intermolecular hydroaminoalkylation reactions of propadiene with selected secondary amines take place in the presence of a 2,6-bis(phenylamino)pyridinato titanium catalyst. The corresponding products, synthetically useful allylamines, are formed in convincing yields and with high selectivities. In addition, propadiene easily inserts into the titanium-carbon bond of a titanaaziridine.

Original publication

DOI

10.1002/chem.202003484

Type

Journal article

Journal

Chemistry - A European Journal

Publication Date

11/11/2020

Volume

26

Pages

14300 - 14304