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Grubbs' catalyst [Cl2Ru{P(C2H11)2}2 = CHPh] can be used to synthesize borane complexes of cyclic phosphanes by ring-closing metathesis reactions. This strategy has been applied, for example, to the preparation of a borane-protected bisphosphanes [Eq. (1)].

Original publication

DOI

10.1002/1521-3773(20000717)39:14<2491::AID-ANIE2491>3.0.CO;2-H

Type

Journal article

Journal

Angewandte Chemie - International Edition

Publication Date

17/07/2000

Volume

39

Pages

2491 - 2493